New phthalocyanine dyestuffs



3,@3Z,Z? ?aterrted Mar. 19, R363 NEW PHTHALOCYANKNE DYESTUFF S Eugen Johann Koller, Binningen, Switzerland, assignor to Ciba Corporation, a corporation of Delaware No Drawing. Filed Aug. 12, 1957, Ser. No. 677,798 Claims priority, application Switzeriand Aug. 17, 1956 1 @iaina. (Cl. 266-242) The present invention provides new, water-soluble phthalocyanine dyestufis which contain a halogen-triazine residue linked through a nitrogen bridge, and more especially phthalocyanine dyestuffs which contain at least two sulfonic acid groups and at least one substituent of the formula CDr hi-I SOz-DRNA in which A is a halogenated triazine residue, 11 is a whole number and preferably 1, R is a divalent organic residue, and D is an oxygen atom or a nitrogen bridge, for example, the phthalocyanine dyestuffs of the formula in which Q is the residue of a phthalocyanine, R is a divalent organic residue and preferably an alkylene or arylene residue, D is an oxygen atom or a nitrogen bridge, X is a bridge of the formula in which m is a whole number, Z is a chlorine atom or a substituted hydroxyl or an amino group which may be substituted, and n is a whole number not greater than 4, and in which the residues Q, R and Z together contain at least two sulfonic acid groups.

The invention also provides a process for the manufacture of the aforesaid water-soluble phthalocyanine dyestuffs containing a halogeno-triazine residue, wherein a phthalocyanine dyestuff containing at least one acylatable amino group is condensed with a halogenated triazine in such manner that the condensation product formed contains at least one monohalogenor dihalogentriazine residue.

Phthalocyanine dyestuffs of the kind defined above suitable as starting materials for the present process are especially those which contain an acylatable amino group in an external nucleus, that is to say, in a nucleus linked to the phthalocyanine nucleus through a bridge member, for example a C0- or -80 group, or a carbonamide group or a sulfonam'ide or sulfonic acid aryl ester group. Instead of being bound in an external nucleus the acylatable group may be linked to an alkylene chain which is bound to the phthalocyanine molecule, for example, by an SO NH group. Either metal-free or metalliferous phthalocyanine dyestuffs of this type can be used. Especially suitable are the complex heavy metal compounds of phthalocyanines containing sulfonic acid groups, for example the iron compounds, and particularly phthalocyanines containing sulfonic acid groups in which cobalt, nickel, copper or iron, that is to say, a heavy metal having an atomic number of 27 to 30, is bound in complex union. Dyestuffs, which give especially good results, are the copper-pht-halocyanines which contain sulfonic acid groups or are sulfonated. Depending on the method of manufacture of the phthalocyanines the sulfonic acid groups are present in the phthalocyanine molecule in 4- or 3-position, respectively, depending on whether 4- sulfophthalic acid is used as starting material or the dyestuff is made by the sulfonation or direct sulfochlorination of phthalocyanine.

Such phthalocyanine dyestuffs, used as starting materials for the present process can be made, for example, by reacting a phthalocyanine sulfonic acid halide (such as can be made, for example, by treating a metal-free or metalliferous phthalocyanine with chlorosulfonic acid, or from the phthalocyanine-di-, -tri-, or tetra-sulfonic acids by reaction with an acid-halogenating agent such as a phosphorus halide, thionyl chloride or chlorosulfonic acid) with an organic compound containing an acylatable hydroxyl or amino group, which comprises in addition to said acylatable group a further acylatable amino group or a substituent which, after reaction with the phthalocyanine sulfonic acid halide, can be converted into such a group. Suitable organic compounds of this kind are thus bifunctional organic compounds such as oxyamines, e.g. oxyethylamine, or diamines, e.g. cyclic, especially aromatic diamines, such as 4:4'-diaminodiphenyl, 4:4- diaminostilbene-Z:2'-disulfonic acid, l:4- or 1:3-diarninobenzene and above all lz4-diaminobenzene-Z-sulfonic acid and 1:3-diaminobenzene-4-sulfonic acid; also suitable are nitranilines or monoacyl derivatives of organic diamines in which case a new NH group is liberated by reduction or hydrolysis after reaction with the phthalocyanine sulfonic acid chloride used. In choosing the starting materials it should be borne in mind that the resulting product must contain preferably at least two sulfonic acid groups apart from at least one acylatable amino group; for this reason the starting material decided upon is, for example, a phthalocyanine dyestufi that contains at least two sulfonic acid halide groups, which is then reacted with an oxyamine or diamine containing sulfonic acid groups. If the oxyamine or diamine chosen is free from sulfonic acid groups, it must be reacted with at most one sulfonic acid halide group of a phthalocyanine sulfonicacid halide that contains at least three such groups. Thus, for example, from 1 mol of a phthalocyanine tetrasulfonic acid chloride and 1 mol or at most 2 mols of one of the said oxyamines or diamines free from sulfonic acid groups, or from their monoacyl derivatives, very valuable phthalocyanine dyestufis are obtained which are suitable starting materials for the present process and contain, after hydrolysis of the unreacted sulfonic acid chloride groups, at least two SO H- groups and at least 1 acylatable amino group. If, on the other hand, use is made of an oxyamine containing sulfonic acid groups-such as 1- amino-3-hydroxybenzene-6-sulfonic acid-01 of a diamine containing sulfonic acid groups-such as 'lz3-diaminobenzene-4-sulfonic acid, 1:4-diaminobenzene-Z-sultonic acid-or of diamino-monoazo dyestuffs containing sulfonic acid groups, or of a monoacyl derivative thereof, more than two of the sulfonic acid chloride groups present in the initial phthalocyanine may participate in the reaction.

Such pht-halocyanine dyestutls containing acylatable amino groups are condensed according to the present process at the amino group with dior tri-halogeno-triazine compounds. From among them may be mentioned,

J apart from cyanuric chloride (2:4:6-trichloro-1:3:S-triazine), the dihalogeno-triazines of the formula in which A is a preferably organic residue, more especial ly the residue of an organic amine.

The dihalogeno-triazines of this constitution can be made by known methods from cyanuric halides such as cyanuric bromide or cyanuric chloride by reacting, for example, 1 mol of cyanuric chloride with 1 mol of an amino or hydroxy compound with or without dyestulf character. Such compounds having dyestuif character are, for example, aminoazo dyestulfs, for example those obtained by coupling a diazo compound (e.g. a diazotised aminobenzene-sulfonic acid or amino-naphthalenesulfonic acid) with a coupling component that contains amino groups (such as cresidine, meta-toluidine, a meta-acylaminoaniline or the like), or those which are obtained by coupling a barbituric acid or a pyrazolone-more especially 1-phenyl-3-methyl-5-pyrazolone-2'-, -3'- or -4- sulfonic acid-with a diazotised monoacyl derivative of an aromatic diamine (such as an acetylamino-aniline sulfonic acid) and hydrolysing the resulting acylaminoazo dyestulf. As compounds having no dyestuif character may be mentioned, for example, ammonia, aliphatic or aromatic hydroxyl compounds such as methanol, ethanol or butanol, phenol, ortho-, metaor para-cresol, 4-secondary butyl-phenol, 4-tertiary amylphenol, dialkylphenols, para-chlorophenol and, above all, organic nitrogen compounds such as methylamine, dimethylamine, ethylamine, diethylamine, isopropylamine, butylamine, hexylamine, phenylamine, tolylamine, 4-chlorophenylamine, N-methyl-phenylamine or cyclohexylamine; furthermore B-chloroethylamine, methoxyethylamine, 'ymethoxypropylamine, ethanolamines, acetamide, butyric acid amide, urea, thiourea, toluene-sulfonamide, glycine, aminocarbonic acid esters such as the methyl or ethyl ester thereof, aminoacetic acid ethyl ester, aminoacetamide, aminoethanesulfonic acids, l-aminobenzene-Z- or -4-methyl-sulfone, l-aminobenzene-Z:S-disulfonic acid, aminobenzoic acids and their sulfonic acids, l-arninobenzene-2-, -3-, or -4-sulfonic acids and their sulfonamides or sulfones, phenylhydrazine and its sulfonic acids. The primary condensation products thus obtained still contain two reactive halogen atoms. Those which are free from sulfonic acid groups are condensed according to the present process only with phthalocyanine dyestuffs that contain at least two sulfonic acid groups, whereas the primary condensation products of Formula 2 containing 1 or 2 sulfonic acid groups in residue A are likewise suitable for reaction with phthalocyanine dyestuffs free from sulfonic acid groups, e.g. with the phthalocyanines containing amino groups, mentioned in US. Patents No 2,479,491 by Norman Hulton Haddock et al. and No. 2,430,052 by Norman Hulton Haddock et a1. or with the dyestuffs containing sulfonic acid groups, which are mentioned in US. Patent No. 2,761,868 by Harold T. Lacey.

The condensation according to the present process of cyanuric chloride, or of a dihalogeno-triazine correspond ing to Formula 2, with the phthalocyanine dyestutf is advantageously made in the presenceof an acid-acceptor such, for example, as sodium carbonate and under conditions such that the finished product still contains at least one exchangeable halogen atom, that is to say, for example, in an organic solvent or at a relatively low temperature in an aqueous medium.

As a rule equally good results are obtained when, instead of the compound of Formula 2, cyanuric chloride is used and after condensation with the phthalocyanine dyestulf, one of the chlorine atoms of the primary condensation product formed is replaced by one of the specified amines suitable for the preparation of the compounds of Formula 2 which may, but need not have dyestuff character.

The particularly valuable dyestuffs of Formula 1 can alternatively be made by a modification of the process described above, wherein a phthalocyanine sulfonic acid halide is condensed with a condensation product of the formula in which R, X and Z have the meanings used in defining Formula 1 and DH is an acylatable hydroxyl or amino group; for this purpose the starting materials must be chosen so that the resulting phthalocyanine condensation product contains at least two SO H groups, e.g. by choosing such compounds of Formula 3 as contain such groups in the residues R and/ or Z, or by reacting as described only one sulfonic acid halide group of a phthalocyanine sulfonic acid halide and after the condensation hydrolysing the remaining sulfonic acid halide groups at 1-1 groups.

The phthalocyanine dyestuffs obtained by the present process and its modification are new; they are valuable, water-soluble dyestuffs suitable for dyeing and printing a wide variety of materials, more especially polyhdroxylated materials of fibrous structure; both synthetic fibers, made for example from regenerated cellulose or viscose, and natural materials, e.g. linen, and above all cotton, are suitable.

The phthalocyanine dyestuffs of the invention applied to the fiber by padding, printing or direct-dyeing, can be fixed by being subjected to an alkaline treatment, for example with sodium carbonate or hydroxide, with an alkaline earth metal hydroxide, with trisodium phosphate or the like, and to a heat treatment. For example,

. the dyeing can be performed at an elevated to slightly elevated temperature (that is to say at 50 to C.) or with a dichlorotriazine dyestuif at normal temperature, eg at about 20 to 50 C. To exhaust the dyebath it is advisable to add simultaneously with the dyestuffs or during the dyeing process more or less neutral, especially inorganic salts, such as alkali metal chlorides or sulfates, if desired in portions. During the dyeing process the dyestuffs react with the polyhydroxylated material being dyed, probably by being fixed by entering chemical bonds. The acid-acceptor can be added to the dyebath at the outset of the dyeing process; advantageously, the alkaline agent is so added that the pH value of the dyebath, which is initially weakly acidic to neutral or weakly alkaline, rises continuously during the whole of the dyeing process.

Instead of preparing the dyebath by introducing the specified dyestuffs and optionally more or less neutral, inorganic salts simultaneously or successively in water, the dyestuffs and the salts can be made up into pastes or preferably dry preparations. Since some of the dyestuffs suitable for the present process are somewhat sensitive to acids and strong alkalies owing to their content of unstable substituents, it has been found advantageous if possible not to add to the dye preparation any salts that display a strongly alkaline reaction in water. On the other hand, it has been found advantageous to isolate and dry the dyestuffs in the presence of salts of weakly alkaline reaction, such as mixtures of monoand di sodium phosphates.

The present phthalocyanine dyestuffs containing at least two sulfonic acid groups and a halogenated triazine residue produce on polyhydroxylated, more especially cellulosic textile materials very valuable, strong and as a rule very full dyeings and prints of outstanding properties of fastness to wetness and very good fastness to light.

In certain cases it may be of advantage to subject the dyeings obtained by the present process to an after-treat ment. Thus, it is advantageous to soap them. Such aftertreatment removes any incompletely fixed dyestuff.

The following examples illustrates the invention, parts and percentages being by weight, and the relationship between parts by weight and parts by volume being the same as that between the gram and the cubic centimetre.

EXAMPLE 1 60 parts of copper-phthalocyanine are introduced into 720 parts by volume of chlorosulfonic acid and the mixture is heated for 2 hours at l4014l. After cooling, the reaction mixture is stirred into ice, and the precipitated sulfochloride is filtered off, thoroughly washed with ice water and further processed in the form of an aqueous paste.

The copper-phthalocyanine sulfochloride (crude product) obtained in this manner is stirred with 300 parts of chopped ice and adjusted to pH 6.5 with dilute caustic soda solution at 0 to 3 C. A solution of parts of l-amino-4-acetylaminobenzene in 580 parts by volume of acetone, as Well as 50 parts by volume of pyridine are rapidly stirred into the sulfochloride. The mixture is stirred for hours at room temperature and the pyridine is then completely removed by steam distillation in an alkaline solution. The dyestufi is isolated by acidification with dilute hydrochloric acid until an acid reaction to Congo has been attained. The acid, moist residue is heated for 1 hour at 100 C. with 1250 parts of water and 50 to 60 parts of concentrated sulfuric acid and then filtered. The dyestufi is dissolved in 1000 parts of hot water with the addition of some alkali and distilled with steam at a pH of 8.5 until volatile amine can no longer be detected and then isolated in usual manner with sodium chloride at a weakly alkaline reaction to brilliant yellow. It may be assumed that the product is a copper-phthalocyanine-monosulfonyl N=(para aminophenyl) -amide-trisulfonic acid.

The sulfonic acid sulfonamide thus obtained is dissolved in 2000 parts of water in the form of its sodium salt and accurately adjusted to pH 7.0. Condensation is performed at 0 to 4 C., with 18.5 parts of cyanuric chloride (precipitated from acetone with ice water), while the pH value of the reaction solution is maintained between 7.5 and 5 by adding 1 N-sodium hydroxide solution. On completion of the condensation 50 parts of sodium bicarbonate are added and the whole is stirred for 12 hour in the cold; the dyestuff is then salted out, filtered off and dried in vacuo at 40 to 45 C.

The dyestufil thus obtained dyes cotton from an aqueous alkaline, .preferably salted, bath according to Examples 27 and very pure greenish blue tints which are fast to light and washing.

A similar dyestulf is obtained by using the copperphthalocyanine sulfochloride described in the lst paragraph of Example 3.

EXAMPLE 2 The copper-phthalocyanine sulfochloride (crude product) obtained as described in the 1st paragraph of Example 1 is stirred into a fine paste with 300 parts of chopped ice and adjusted at pH 7.5 at 0 to 3 C. with dilute sodium hydroxide solution. In quick succession parts of calcium carbonate and a solution of 15 parts of 1-amino-4-acetylaminobenzene in 5 80 parts by volume of acetone are then added, and this reaction mixture is stirred for 20 to 24 hours at room temperature, then adjusted at to C. with dilute hydrochloric acid to react acid to Congo and the precipitated dyestufi is filtered ofl; it is stirred with 1000 parts of water and adjusted with dilute sodium hydroxide solution to a pH of 7.5 to 8 in a manner such that the total volume amounts to about 1500 parts, 90 parts of solid sodium hydroxide are added and the whole is heated for 2 hours at to While thoroughly stirring the mixture at 40 C., its alkalinity is reduced to pH 8.5 with concentrated hydrochloric acid, and steam distillation is then performed. For further purification the dyestutf is once again precipitated with hydrochloric acid to react acid to Congo, filtered off and suspended in water, rendered alkaline with dilute sodium hydroxide solution, and the dyestulf is salted out in the form of its sodium salt with sodium chloride.

Condensation of this aminophthalocyanine-sulfonic acid with cyanuric chloride, performed as described in the 3rd paragraph of example yields a dyestuff which is substantially identical with the product described in Example 1.

When copper-phthalocyanine sulfochloride, prepared as described in the 1st paragraph of Example 3, is used, a similar dyestuff is obtained.

EXAMPLE 3 57.5 parts of copper-phthalocyanine are so stirred into 5 37 parts of chlorosulfonic acid that the temperature does not rise about 30 C., and the mixture is then stirred on for /2 hour at room temperature. The reaction mixture is then raised within 1 /2 hours to a temperature of 130 to 133 C. and maintained at that temperature for 4 hours. It is then stirred cold and, while still being stirred, it is entered into a mixture of 500 parts of water, 280 parts of sodium chloride and 3000 parts of chopped ice. The mixture is then stirred for a short time, filtered, and the filter residue is washed on the suction filter with 600 parts by volume of saturated sodium chloride solution and 200 parts of ice. In this manner a copperphthalocyanine sulfochloride is obtained which is further processed as a moist, acid paste (crude product); most probably it is a mixture of copper-phthalocyanine- 3:3:3-trisulfochloride-3"-monosulfonic acid and the corresponding copper-phthalocyanine-disulfochloride-disulfonic acid.

The sulfochloride obtained in the manner described is stirred as an acid paste with 300 parts of chopped ice and adjusted to pH 6.5-7.0 at 0 to 3 C. with dilute, sold sodium hydroxide solution. The sulfochloride paste neutralised in this manner is mixed with 5 parts of sodium carbonate and a solution of 14 parts of 4-aminoformylaniline in 500 parts of water, and immediately afterwards another 15 parts of sodium carbonate are added. ,The reaction mixture is stirred for 24 hours at 20-23" C., acidified with hydrochloric acid, and the precipitated dye acid is filtered off. For hydrolysis the residue (acid reaction to Congo) is suspended in 1000 parts of water, dilute sulfuric acid (containing 60 parts of concentrated H 50 is added in a manner such that the total volume does not exceed 1500 parts, and the whole is heated for 1 hour at C. After cooling, the mixture is filtered and the residue once more suspended in water. The suspension is rendered alkaline with sodium hydroxide solution, subjected to steam distillation to remove some volatile amine, and the dyestuff is salted out with sodium chloride as its sodium salt at a pH value of 7.5.

The dyestuff is diluted in 2000 parts of water and the pH is accurately adjusted to 7.0. The .dyestuff is then condensed at 04 C. with 18.5 parts of cyanuric chloride precipitated from acetone with ice water. During the condensation the pH value of the solution is kept at 5.0 to 7.5 by adding 1 N-sodium hydroxide solution. After completion of the condensation 200 parts by volume of 1 N-ammonia solution are added to the cold reaction solution, the whole is heated for 2 hours at 35 to 40 C., and the dyestuff is isolated from the solution which has a weak alkaline reaction to brilliant yellow.

The resulting dyestult dyes cellulose fibers by the process described in Example 25 brilliant blue tints fast to washing.

To produce the dichloro-triazine dyestuff, completion of the cyanuric chloride condensation is followed by the addition of 25 to 50 parts of sodium bicarbonate, stirring for /2 hour at to C., and salting out of the dyestuff with sodium chloride.

The dyestuff obtained in this manner dyes cellulose fibers by the dyeing process described in Example and 27 brilliant blue tints that are fast to washing.

Similar dyestuffs are obtained when copper-phthalocyanine-3:4'-4:4-sulfonic acid is converted into the sulfochloride, otherwise proceeding in identical manner.

EXAMPLE 4 Copper-phthalocyanine sulfo-chloride (crude product) obtained as described in the 1st paragraph of Example 3 is stirred with 300 parts of chopped ice and adjusted at Oto 3 C. with dilute sodium hydroxide solution to a pH value of 6.5 to 7.0. The neutralised sulfochloride is mixed with 25 parts by volume of a solution of 20 parts of calcined sodium carbonate in 100 parts of water. The whole is stirred for a short time and immediately thereafter a neutral solution, heated at C., of 47.5 parts of the secondary condensation product from 1 mol of cyanuric chloride, 1 mol of 1:3-diaminobenzene-4-sulfonic acid and 1 mol of ammonia in 1200 parts of water is added, and the mixture is stirred on at room temperature. By gradually adding the remainder of the sodium carbonate solution the pH of the reaction mixture is maintained at between 6.5 and 7.8. In all, the mixture is stirred for 24 hours and then heated at to C. When the pH value has remained constant for 1 to 2 hours without any further addition of dilute sodium hydroxide solution, the dyestufi is salted out with sodium chloride. The dyestuff thus obtained dyes cellulose fibers by the process described in Example 26 brilliant blue tints that are fast to washing.

Similar dyestuffs are obtained when the sulfochloride is reacted with a smaller quantity, that is to say about 31 parts, or with a larger quantity, for example 60 parts, of the cyanuric chloride condensation product used in the present example.

The secondary condensation product from cyanuric chloride, 1:3-diaminobenZene-4-sulfonic acid and ammonia, can be replaced by the secondary condensation product from 1 mol of cyanuric chloride, 1 mol of 1:4- diaminobenzene-Z-sulfonic acid and 1 mol of ammonia, whereby a similar dyestufi is obtained.

EXAMPLE 5 A sulfochloride paste which has been obtained from 57.5 parts of copper-phthalocyanine according to the 1st paragraph of Example 3 and neutralised as described in the 1st paragraph of Example 4 is mixed with a solution of 13.6 parts of 4-aminoformylaniline in 500 parts of water, and 20 parts of sodium carbonate are strewn in. This reaction mixture is stirred for 24 hours at room temperature. 'Ihe dyestuif is then isolated in the cold with hydrochloric acid and filtered off.

To hydrolyse the formyl group, the dye is converted into its sodium salt and sufiicient water is added to produce a total volume not exceeding 1500 parts; 60 parts of solid sodium hydroxide are added to the cold solution, and the whole is finally heated for to 60 minutes at 85 to 90 C. The excess of alkali is neutralised with hydrochloric acid, the whole is subjected to steam distillation in an alkaline solution, and the dystuff is isolated as its sodium salt by adding sodium chloride at a pH of 7.5.

To condense with cyanuric chloride, the dyestufi thus obtained is dissolved in 2000 parts of Water and the solution is adjusted to pH=7.0. Condensation is performed with 17.0 parts of finely divided cyanuric chloride at 0 to 4 C. as described in Example 1. On completion of the condensation, 25 parts of sodium bicarbonate are 8 added, and the whole is stirred on for /2 hour The dye stuff is isolated as described in the preceding examples and dried at 45 F. The dyestuft thus obtained dyes cellulose fibers by the dyeing process described in Exampics 25 and 27 brilliant blue tints that are fast to washing.

When the dyestufi is treated with ammonia, a new, similar dyestuff is obtained which yields on cellulose fibers very similar blue tints by the dyeing process described in Examples 25 and 26. This ammonia treatment is conducted as follows:

About 118 parts (20.1 mol) of the dyestuil are dissolved in 2000 parts of cold water, 200. parts by volume of 1 N-ammonia solution are added, and the wholeis stirred for 2 hours at 35 to 40 C. The dyestuft thus formed is isolated in usual manner.

EXAMPLE 6 Copper-phthalocyanine sulfochloride obtained from 60 parts of copper-phthalocyanine as described in the first paragraph of Example 3 is stirred with 100 parts of chopped ice and 100 parts of water into a very fine suspension and the pH value adjusted with dilute sodium hydroxide solution to 7.0, the temperature not being allowed to exceed +5 C.

At the same time a neutral suspension heated to 20 -C. of 47.5 parts of. the secondary condensation product from 1 mol of cyanuric chloride, 1 mol of 1:3diaminobenzene-4-sulfonic acid and 1 mol of ammonia is prepared, the total volume of the amine component being 950 parts by volume.

5.0 parts of calcined sodium carbonate are added, while stirring well to the neutralised sulfochloride paste at the same tirne as the aminochlorotriazine suspension. The temperature rises from 5 C, to 13 to 14 C. As soon as the pH value of the reaction mixture has attained 7.0 to 7.2, a further 15 to 16 parts of sodium carbonate are added. The whole is stirred from 5 to 7 hours at 20 to 21 C., 20 parts by volume of concentrated ammonia are added, and stirring is continued for 12 to 14 hours at room temperature.

If necessary, the ammoniacal reaction solution is brought back to a pH value of 7.5 to 7.7 by cautiously adding dilute hydrochloric acid. After heating the whole for one hour at 30 to 35 C., the dyestufif is isolated with sodium chloride from the reaction medium brought to weakly alkaline reaction to brilliant yellow.

EXAMPLE 7 0.1 mol of the copper-phthalocyanine sulfonic acid whose molecule contains 2.5 to 3 sulfonic acid groups, obtained in the solid phase by sulfonating copper-phthalocyanine (for example according to German Patent No. 825,112) is added in the cold to 500 parts of chlorosulfonic acid. The temperature should not rise above 30 C. The mixture is stirred for /2 hour at C., and thereafter 180 parts of thionyl chloride are added dropwise in the course of 45 minutes. The Whole is stirred at 82 C. until the formation of the sulfochloride is complete, and the mixture is then poured out on ice and water. The precipitated sulfochloride is isolated by filtration and washed with water on the filter.

By stirring with 300 parts of chopped ice a sulfochloride paste is prepared which is mixed with 18.8 parts of 1z4-diaminobenzene-Z-sulfonic acid dissolved in 400 parts of water with the addition of parts by volume of 1 N-sodium hydroxide solution. 50 parts by volume of pyridine are added to the reaction solution, and the mixture is stirred for 24 hours at room temperature. The pyridine is completely removed by steam distillation in an alkaline solution, and the dyestufi" is isolated as its sodium salt in the usual manner. This dyestufi is then condensed at 0 to 5 C. with 18.5 parts of cyanuric chloride as described in Example 3. On completion of the condensation, the whole is stirred in the cold with, 50 parts of sodium bicarbonate at 2 0., and the dyestulf is salted out with sodium chloride at a pH of 7.3

and then dried at 45 C. In this manner a dyestuff is obtained which by the dyeing process described in Example 25 produces on cellulose fibers brilliant blue tints fast to washing.

EXAMPLE 8 The sulfochloride obtained as described in the 1st paragraph of Example 3 from 28.75 parts of copper-phthalocyanine is neutralized at to 3 C. as described in the 1st paragraph of Example 4.

35.5 parts of the product of the formula are dissolved in Water with the addition of 1 N-sodium hydroxide solution at a pH of 7.5 to produce a volume of 550 parts. This amino-chlorotriazine solution is added to the neutralised, vigorously stirred sulfochloride sus pension. By adding 8 parts of anhydrous sodium carbonate in 4 portions the pH value is kept constantly above 7.0. After 8 hours reaction at 18 to 21 C., 10 parts by volume of concentrated ammonia are added, and the hole is stirred for another 10 hours at room temperature, heated at a pH of 7.5 to 7.7 for 1 hour at 35 to 40 C., and the dyestuif is then isolated in usual manner.

When the condensation is performed, instead of with the product of the formula in the 2nd paragraph above, with 25.5 parts of the product of the formula (and following the same procedure);

v IIQHQ A salting out with potassium chloride furnishes a dyestuff, which dyes cotton by the process described in Example 28 brilliant blue tints fast to Washing.

EXAMPLE 9 Starting from 30 parts of copper-phthalocyanine the copper-phthalocyanine-sulfochloride mixture described in the 1st paragraph of Example 3 is prepared as described in that passage.

The resulting sulfochloride (crude product) is stirred into a very fine suspension with 50 parts of chopped ice and 50 parts of water and adjusted at 0 to C. with dilute sodium hydroxide solution to pH 7.3.

At the same time 7.15 parts of N-formyl-p-aminophenol are dissolved in 250 parts of cold water with the addition of 52 parts by volume of 1 N-sodium hydroxide solution.- This solution is tipped into the neutralised sulfochloride and 4 to 5 parts of anhydrous sodium carbonate are then added to the mixture. The reaction mixture is stirred for 24 hours at 20 to 22 C. At 35 C. hydrochloric acid is then added to produce a distinct acid reaction to Congo, and the precipitated dye acid is filtered off. To hydrolyze it, it is stirred in the form of a moist, acid paste with 400 parts by volume of 1 N-hydroc-hloric acid and heated for 2 hours at 85 to 90 C. After cooling, the dyestufi is once again filtered ofi, suspended in 1000 parts of hot water and rendered alkaline (pH 7.8) with dilute sodium hydroxide solution. The dyestuft" solution is heated to 35 to 40 C.; after it has retained a pH of 7.6 for 1 /2 hours without any more alkali being added, the dyestutf is salted out with sodium chloride.

This dyestuff is dissolved in 1200 parts of water and '10 condensed at 0 to 4 C. with 9.3 parts of cyanuric chlo ride (which has been precipitated from acetone with ice Water), during which operation the pH is maintained at between 5.5 and 7.8 by adding 1 N-sodium hydroxide solution.

On completion of the condensation 12.5 parts of sodium bicarbonate are added, and the whole is stirred for /2 hour at 2 to 3 C. The dyestuff is then salted out with sodium chloride and dried in vacuo at 45 to 50 C.

EXAMPLE 10 In the course of 15 minutes 28 parts of chlorosulfonic acid are added dropwise at C. to a vigorously stirred melt of 250 parts of anhydrous aluminum chloride and 40 parts of sodium chloride, and the whole is stirred for a further 10 minutes at 120 C. In the course of 25 minutes 19.7 parts of dry tetrasodium salt of copperphthalocyanine-tetrasulfonic acid (prepared by alkaline hydrolysis of copper-phthalocyanine-3 3 3 ":3 "-tetrasulfochloride) are added. The temperature of the reac tion mixture is raised within 45 to 50 minutes to 160 to 161 C., and it is stirred for 3 hours at that temperature. Then, while stirring, the mixture is allowed to cool to to C. and then poured on to a mixture of ice and water, suctioned oif and the filter residue is washed on the filter with 500 parts by volume of sodium chloride solution of about 5 percent strength and dried in vacuo at 70 C. A chlorinated copper-phthalocyanine-tetrasulfonic acid is obtained.

For conversion into the sulfochloride the product thus obtained is stirred into 320 parts of chlorosulfonic acid and heated for 4-5 hours at 100 to 103 C. The cooled reaction mixture is poured on to sodium chloride and chopped ice, stirred for a short time and then suctioniiltered. The residue is washed on the filter with 200 parts by volume of sodium chloride solution of 10 percent strength. The sulfochloride thus prepared is stirred into a fine paste with 60 parts of ice and adjusted at 0 to 3 C. with dilute sodium hydroxide solution to pH=7.0 to 7.5. This neutralised sulfochloride is mixed with 4 parts of calcined sodium carbonate and then with 2.8 parts of para-amino formylanilide dissolved in 100 parts of water. The whole is stirred for 20 to 24 hours at room temperature and acidified at 40 C. with dilute hydrochloric acid to attain an acid reaction to Congo. To hydrolyze the still moist, acid dye acid it is pasted with 200 parts of Water, 10 to 12 parts of concentrated sulfuric acid in 50 parts of water are added, and the Whole is vigorously stirred for 1 hour at 100 C. The dyestutf is then filtered ed and isolated in the form of its sodium salt as described in the 2nd paragraph of Example 1.

The resulting chlorinated copper-phthalocyanine-sulfonyl-(para-aminophenyl)-amide-sulfonic acid is then condensed With cyanuric chloride as described in the 3rd paragraph ofEx-ample 1. On completion of the condensation the reaction mixture is rendered alkaline with bicarbonate and stirred on for /2 hour at 5 C.; the dyestuir" is then salted out with sodium chloride and dried in vacuo at 45 to 50 C.

The dichlorotriazine dyestuff thus obtained dyes cellulose fibers according to the dyeing process described in Example 25 or 27 greenish blue tints fast to washing.

EXAMPLE 11 19.7 parts of sodium copper-phthalocyaninel:4:4":4'- tetrasulfonate are stirred with cooling into 200 parts by volume of chlorosulfonic acid, and the mixture is stirred for 15 minutes at room temperature. Inside of 1 hour the reaction mixture is raised to an internal temperature 1 1 of 130 to 132 C. and stirred on at that temperature for 45 to 60 minutes. The cooled sulfochloride is poured on to 1400 parts of chopped ice, 200 parts of water and 170 parts of sodium chloride, filtered, and Washed with a mixture of 300 parts by volume of saturated sodium chloride solution and about 100 parts of ice.

This sulfochloride is thoroughly stirred as an acid, moist paste with 30 parts of water and 30 parts of ice and then adjusted with dilute sodium hydroxide solution at to 3 C. to a pH value of 7.5. The sulfochloride neutralised in this manner is immediately mixed with a neutral suspension, having a temperature of 20 C., of 9.5 parts of the secondary condensation product from 1 mol of cyanuric chloride, 1 mol of 1:3-diaminobenzene-4-sulionic acid and 1 mol of ammonia in water, the total volume of the suspension being 180 parts by volume. The reaction mixture is stirred at 20 C., a total of 6 parts of calcined sodium carbonate is strewn in in portions so that the pH of the reaction mixture does not drop below 7.0. After 8 to 9 hours reaction at 20 C., 5 parts by volume of concentrated ammonia are added, and the mixture is stirred for another 14 hours at room temperature, during which some of the unhydrolysed sulfochloride groups are converted into sulfonamide groups. The alkalinity is reduced to 7.7 by means of dilute hydrochloric acid, the whole is heated at 35, and the dyestutf is salted out with sodium chloride.

On cotton brilliant blue prints are obtained which are so fixed as to be fast to washing.

EXAMPLE 12 19.7 parts of sodium copper-phthalocyanine-3:424": 4-tetrasulfonate are stirred into 160 parts by volume of chloro sulfonic acid in a manner such that the temperature is prevented from rising above 20 C. The mixture is then stirred for 15 minutes at room temperature and raised in the course of 1 hour to an internal temperature of 130 to 132 C., kept at that temperature for 1 hour, allowed to cool, and the suifochlorination mixture is poured on to 1400 parts of ice, 170 parts of sodium chloride and 200 parts of Water. The sulfochloride formed is filtered off and washed with a mixture of 300 parts by volume of saturated sodium chloride solution and 100 parts of ice.

The sulfochloride is stirred with 30 parts of water and 30 parts of ice into a very fine paste and adjusted at 0 to 3 C. with dilute sodium hydroxide solution to a pH of 7.5. This neutralised sulfochloride is then mixed with a neutral suspension, heated at 20 C., of 9.5 parts of the secondary condensation product from 1 mol of cyanuric chloride, 1 mol of 1:3-diaminobenzene-4-sulfonic acid and 1 mol of ammonia in water, the total volume of the suspension being 180 parts by volume. This reaction mixture is stirred at room temperature for 7 hours While strewing in 6 parts of calcined sodium carbonate in 5 portions so that the pH is prevented from dropping be low 7.0. After that time, 5 parts by volume of concentrated ammonia are added and the whole is stirred on for 12 hours at room temperature. The alkalinity is reduced to 7.7 by adding dilute hydrochloric acid, and the dyestuif is isolated with sodium chloride and dried at 60 C. in vacuo.

On cotton this dyestuti produces brilliant blue prints which are so fixed as to be fast to Washing.

EXAMPLE 13 40.8 parts of copper-phthalocyanine-3:3:3-trisulfonic acid (obtained by treating copper-phthalocyanine with oleum) are so stirred into 250 parts of chlorosulfonic acid that the temperature is prevented from rising above 25 to 30 C. The whole is then heated to 80 C. and stirred at that temperature for /2 hour. In the course of 1 hour 56 parts by volume of thionyl chloride are added dropwise, with the temperature dropping to 73 C. When all the thionyl chloride has been added, the mixture is heated for 75 minutes at 80 to 82 C. The cooled reaction 12 mass is poured on to ice, filtered and then thoroughly washed with water. The sulfochloride formed is ob tained in the form of a weakly acid, aqueous paste.

Half of the sulfochloride thus obtained is intimately stirred with 25 parts of ice and 25 parts of water, and with dilute sodium hydroxide solution adjusted at 0 to 4 C. to apH of 7.5.

At the same time a suspension is prepared from 11.8 parts of the secondary condensation product from 1 mol of cyanuric chloride, 1 mol of l:3-diaminobenzene-4-sulfonic acid and 1 mol of ammonia in water, said suspension having been cautiously neutralised with the sodium hydroxide solution and adjusted at 20 C. to a total volume of 250 parts by volume.

The neutralised sulfochloride is mixed with 2 parts of calcined sodium carbonate, and the suspension of the aminotrichlorotriazine component is tipped in. The whole is stirred for 20 hours at 30 C. and another 3-4 parts of calcined sodium carbonate are added in 3 portions as soon as the pH of the reaction mixture has dropped below 7.0. When the pH has remained constant at 30 to 35 C. for 1 hour without any further addition of alkali, the dyestuft is isolated with sodium chloride, washed with salt water and dried at 60 C. in vacuo.

The dyestutf dyes cotton by the process described in Example 28 brilliant blue tints.

EXAMPLE 14 The sulfochloride (crude product) obtained from 30 parts of copper-phthalocyanine as described in the 1st paragraph of Example 3 is stirred in the usual manner with 50 parts of water and 50 parts of ice and neutralised with dilute sodium hydroxide solution.

A suspension is prepared by pasting 19.6 parts of the secondary condensation product from 1 mol of cyanuric chloride, 1 mol of l:3-diaminobenZene-4-sulfonic acid and 1 mol of aniline with 200 parts of water and the pH is adjusted with l N-sodium hydroxide solution to 7.5 The final volume at 20 C. should be about 450 parts by volume.

13.5 parts of calcined sodium carbonate are strewn into the well-stirred, neutralised sulfochloride suspension, and at the same time the aminochlorotriazine component is added. The mixture is stirred for 24 hours at 20 to 22 C., then heated at 35 to 40 C. and the dyestutf is isolated as described in the 1st paragraph of Example 4.

A dyestuif is thus obtained which dyes cellulose fibers by the process described in Example 26 brilliant greenish blue tints which are so fixed as to be fast to washing.

EXAMPLE 15 A sulfochloride paste prepared from 60 parts of copper-phthalocyanine as described in the 1st paragraph of Example 3 and neutralised as described in the 1st paragraph of Example 4 is mixed with 15 parts of l-amino- 4-acetylaminobenzene dissolved in 580 parts of acetone and 50 parts of pyridine. After 24 hours reaction at room temperature the pyridine is completely removed by steam distillation in an alkaline solution. At 40 C. concentrated hydrochloric acid is added to the mixture to render it acid to Congo. The precipitated dye is then filtered and suspended in about 900 parts of water, dissolved by adding sodium hydroxide solution and rendered alkaline to brilliant yellow. Hydrolysis is performed by adding parts of solid sodium hydroxide, the volume is made up to 1500 parts, and the whole is heated for 2 hours at 90 C. The dyestutf is once more precipitated with concentrated hydrochloric acid, again dissolved with the addition of alkali, and steam is introduced until all the amine volatile with steam has been removed. The dyestuff is salted out with sodium chloride at a pH value of 7.2-7.5. The product so obtained is probably a copper-phthalocyanine-trisulfonic acid monosulfonyl-N-(paminophenyl)-amide.

3.78 parts of cyanuric chloride are dissolved in 13 parts of acetone and while being thoroughly stirred and cooled mixed with a solution to 2 C.) of 3.46 parts of 1-amino-4-benzenesul-fonic acid (in the form of its sodium salt) in 200 parts of water. At the same time 20 parts by volume of. 1 N-sodium hydroxide solution are added dropwise at 0 to 2 C. to keep the pH of the reaction mixture at to 7. Condensation progresses very rapidly.

This condensation product is added to a neutral solution of 0.02 mol of copper-phthalocyanine-sulfonic acidmono-sulfonyl-N-(para-aminophenyl)-amide in 500 parts of water. The mixture is heated at 35 to 40 C. and, as in the first condensation, its alkalinity is maintained at a pH value between 5 and 7.5 by the dropwise addition of 1 N-scdium hydroxide solution. After 1 /2 to 2 hours the condensation is complete, and the dyestuff is salted out with sodium chloride from a solution weakly alkaline to brilliant yellow paper.

By the process described in Example 28 pure blue tints are obtained on cotton which are fast to washing.

EXAMPLE 16 5.15 parts of 4-amino-4-hydroxy-l l-azobenZene-5'- carboxylic acid (in the form of its sodium salt) are dissolved in 200 parts of water and 100 parts of acetone and cooled to 0 to 2 C. This solution is added to a solution of 3.78 parts of cyanuric chloride in 100 parts of acetone. At 0 to 2 C., while stirring well, 20 parts by volume of l N-sodium hydroxide solution are added dropwise, while the pH is kept between 5 and 7.0. On completion of the condensation, when no more free amino component can be detected, a neutral solution of 0.02 mol of copperphthalocyanine-trisulfonic acid-monosulfonyl N (paraaminophenyl)-amide in 500 parts of water is added, and the whole is immediately heated to 40 C. As described in connection with the first condensation, the pH value is maintained between 6 and 7 by the dropwise addition of 18 to 20 parts by volume of 1 N-sodium hydroxide solution. On completion of the condensation the dyestutf is salted out with sodium chloride from a solution Weakly alkaline to brilliant yellow and dried in vacuo at 60 to 65 C.

The resulting dyestuir dyes cotton by the process described in Example 28 brilliant green tints which are so fixed as to be fast to Washing.

By the chrome-printing method green prints are obtained on cotton.

phthalocyanine-sulfochloride is prepared as described in the 1st paragraph of Example 3. A quarter of the product thus obtained (about 0.025 mol) is stirred into a very fine paste with 50 parts of ice and adjusted at 0 to 3 C.

with dilute sodium hydroxide solution at a pH of 7.5. 6.9 parts of 4:4-dia-minodiphenyl-3-sulfonic acid are dissolved in 200 parts of water with the addition of 26.5 parts by volume of l N-sodium hydroxide solution; this solution is added to the neutralised sulfochloride, and immediately 5 pants of calcined sodium carbonate are strewn in. The reaction mixture is stirred for 20 hours at 20 C., then heated up to 60 to 63 C. and stirred for some time at that temperature at a strong alkaline reactionto brilliant yellow. The alkalinity is brought down to 7.5 and the dyestufi is salted out with sodium chloride as completely as possible.

4.6 parts of cyanuric chloride are dissolved with heating in acetone, poured on to ice, isolated by filtration, and suspended in chopped ice. While keeping this cyanuric chloride suspension stirred, it is mixed with a solution in 700 parts of water of the dyestufi described above. By adding dropwise 23 parts by volume of l N-sodium hydroxide solution at 4 to 6 C. the pH is maintained between 5 and 7.2. On completion of the condensation the dyestutf solution is mixed with 27.5 parts by volume of 2 N-arnmonia solution, and the whole is heated for 2 /2 14 hours at 30 to 35 C. At a pH of 7.5 the dyestuif is salted out with sodium chloride and dried in vacuo at 50 to 55 C.

By the dyeing process described in Example 28 this dyestuif furnishes brilliant blue dyeings fast to washing.

EXAMPLE 18 in 1000 parts of water. The reaction mixture is immediately heated to 30-33 C. while being thoroughly stirred. By strewing in in portions a total of 12 parts of calcined sodium carbonate the pH is kept from dropping below 7, the whole being stirred for 6 hours at 30 to 33 C. and then for 12 horns at room temperature and then heated to 35 to 38 C. When the reaction mixture has remained constant for 1 hour without any further sodium carbonate having been added, the dyestutf is salted out with sodium chloride at a pH of 7.7, and dried as usual.

In this manner a dyestui'f is obtained which, by the dyeing process described in Examples 25, 26 and 28 dyes cellulose fibers brilliant bluish green tints fast to Washing.

EXAMPLE 19 60 parts of copper-phthalocyanine are converted into the .sulfochlor-ide as described in the 1st paragraph of Example 3. A quarter of the product thus obtained (about 0.025 mol) is stirred at 0 to 3 C. with 25 parts of Water and 25 parts of ice and adjusted to pH=7.3 to 7.5 by means of dilute sodium hydroxide solution.

5.7 parts of 1-( 3'-aminophenyl) -5-pyraZolone-3-carboxylic acid are dissolved in 15 parts by volume of pyridine and 30 parts of Water, and this solution is thoroughly stirred into the neutralised sulfochloride. After '24 hours reaction at room temperature the reaction mixture is treated with 50 parts by volume of saturated sodium chloride solution and in the cold rendered acid to Congo with S-N-hy-drochloric acid. The precipitated dyestufi is filtered olf, suspended in water and heated at 60 C. in a solution of strongly alkaline reaction to brilliant yellow until any sulfochloride groups not previously hydrolysed have been hydrolysed. To remove the pyridine the alkaline solution is treated with steam, and at a pH of 7.3 the dyestuff is isolated as completely as possible with potassium chloride and saturated sodium chloride solution.

11.8 parts of the product of the formula are stirred into a fine paste with 300 parts of Water and ice and adjusted to pH=7.5 with 1 N-sodium hydroxide solution. 12.5 parts by volume of 2 N-nitrite are added to said solution, cooled to5 .C. and while it is being vigorously stir-red 7 .5 parts by volume of concentrated hydrochloric acid are tipped in. The mixture is stirred at 10 to 12 C. to complete the diazotisation, and the diazo component is added to an alkaline solution of the dyestufi described above in 200 parts by volume of water and 12 parts of calcined sodium carbonate. On completion of the coupling reaction the dyestutf is salted out with so dium chloride, washed with 200 parts of saturated salt water and dried in vacuo at 55 to 60 C.

The dyestufl? thus obtained yields on cotton by the method described in Example 28, as well as by printing, yellowish green tints which are fast to washing.

EXAMPLE 20 60 parts of copper-phthalocyanine are converted into the sulfochloride as described in the 1st paragraph of Example 3. Half of the product thus obtained (about 0.05 mol) is neutralised at to 3 C. as described in the 1st paragraph of Example 4.

6.78 parts of monoacetyl-ethylene diamine are dissolved in 250 parts of water. While stirring the neutral sulfochloride suspension well, 11 parts of anhydrous sodium carbonate are strewn in, and the amine solution is added. The whole is stirred for 24 hours at 20 to 22 C. Hydrolysis is performed by adding 60 parts of sodium hydroxide (100%), the volume is made up to 1000 parts and the mixture heated for 2 /2 hours at 85 to 90 C. At 40 C. the alkalinity is adjusted with concentrated hydrochloric acid to pH=8.5, and the mixture is subiected to steam distillation to remove all amine volatile with steam. From the solution, which is weakly alkaline to brilliant yellow, the dyestufit can be isolated with sodium chloride. Half of the dyestuif thus obtained is dissolved in water, cooled to O to 2 C., and condensed with 4.6 parts of cyanuric chloride at 6-8 C., which has been precipitated from acetone with ice water, filtered and slurried with ice. The pH of the reaction solution is maintained at 5.5 to 7.5 by the dropwise addition of 25 parts of 1 N- sodium hydroxide solution. On completion of the condensation 275 parts by volume of 2 N-ammonia-solution are added, and the mixture is heated for 2 /2 to 3 hours at 35 to 40 C. By adding a small amount of hydrochloric acid the alkalinity is brought down to 7.5, and the dyestuff is salted out with sodium chloride and dried at 55-60 C. in a water-jet vacuum.

The dyestutf prepared in this manner dyes cotton by the method described in Example 26 brilliant blue tints fast to washing.

EXAMPLE 21 11.5 parts of cobalt-phthalocyanine are added to 115 parts of chlorosulfonic acid, and the mixture is stirred for 15 minutes at room temperature. The reaction mixture is then heated and stirred for 2 hours at 130 to 132. After cooling, the mixture is poured on to 56 parts of sodium chloride, 100 parts of water and 600 parts of chopped ice, filtered, and washed with a mixture of 120 into a very fine paste with parts of ice and at 0-3 C. adjusted to pH 7.0 with dilute sodium hydroxide solution. This sulfochloride paste is mixed with 5.0 parts of calcined sodium carbonate and almost simultaneously with a neutral suspension of 9.5 parts of 2-chloro-4-amino-6- (3-aminophenyl) -amino-l 3 5 -triazine-4'-sulfonic acid in 150 parts of water. The reaction mixture is stirred for 20 to 22 hours at room temperature, heated to 35 to 37 C. and maintained at that temperature for 2 hours. The dyestuff is isolated with sodium chloride at a pH value of 7.5 to 7.6.

The dyestutr' obtained in this manner dyes cotton greenish blue tints by the method described in Example 26.

A similar dyestutf is obtained when 11.8 parts of nickelphthalocyanine are used instead of the specified 11.5 parts of cobalt-phthalocyanine.

EXAMPLE 22 Copper-phthalo-cyanine-sulfochloride is prepared as described in the lst paragraph of Example 3 by treating 57.5 parts of copper-phthalocyanine with chlorosulfonic acid.

The paste obtained in this manner is stirred with 100 parts of ice and 100 parts of water and neutralised at 0-3" C. with dilute sodium hydroxide solution so that a slightly alkaline reaction is obtained with brilliant yellow paper. The .neutralised sulfochloride paste is mixed with 20 parts by volume of a sodium carbonate solution obtained by dissolving 20 parts of sodium carbonate in 100 parts of water. Immediately thereafter, a neutral solution of 43 parts of the secondary condensation product from 1 mol of cyanuric chloride, 1 mol of methanol and 1 mol of l:3-diaminobenzene-4-sulfonic acid in 900- 1000 parts of water is added. The pH'of the reaction mixture is kept at a constant value of 6.8 to 7.8 by continuously adding dropwise the remainder of the sodium carbonate solution at room temperature. The whole is stirred for 24 hours at room temperature and then heated to 35 to 40 C. When the dyestuff solution has remained alkaline to brilliant yellow for l to 2 hours at 35 C. without any more sodium carbonate solution being added, the dyestuff is isolated with sodium chloride and dried.

The dyestuff thus obtained dyes cellulose fibers by the method described in Example 26 tints that are fast to light and washing.

EXAMPLE 23 From parts of copper-phthalocyanine the sulfochloride is prepared as described in the 1st paragraph of Example 3. A quarter of the product thus obtained (about 0.025 mol) is stirred into a very fine paste, with 25 parts of ice, and the paste is well stirred and neutralised at 0-3 C. with cold sodium hydroxide solution of about 15 percent strength to attain a pH value of 7.3.

21.0 parts of the monoazo dyestufi of the formula parts by volume of saturated salt water and 60 parts of ice. The sulfochloride obtained in this manner is-Stirmd .prepared by coupling a solution, rendered alkaline with sodium carbonate, of diazotised 2-chloro-4-(4"-sulfophenylamino) 6 (4 sulfo 3' amino) phenylamino1 :3 :4-triazine with 1-(3-aminophenyl) -5-pyrazolone-3-carboxylic acid-are stirred with water into a fine paste of Weakly alkaline reaction to brilliant yellow paper, the total volume amounting to 650 parts. This yellow component is added to the well-stirred neutralised sulfochloride, 2 parts of calcined sodium carbonate are strewn in, and the reaction mixture is immediately heated to 30-35 C. The pH value rapidly drops to 7.0, Whereupon '1 part of sodium carbonate is added. When this amount if alkali has been consumed, another 1-1.5 parts of sodium carbonate are added. Stirring is performed in all for 6-7 hours at 30-35 C. and then overnight at room temperature. When the pH has stabilised itself at 7.5 to 7.7, the dyestutf is isolated at 35 C. with sodium chloride from a solution of a weakly alkaline reaction to brilliant yellow and dried in vacuo at 60 C.

The resulting product dyes cotton by the method described in Example 26 yellowish green tints.

EXAMPLE 24 20 parts of copper-phthalocyanine are vigorously stirred into 282 parts of oleum of 10 percent strength. The reaction mixture is slowly heated to 80 C., and in the course of 5 to 10 minutes parts of w-hydroxymethylphthalic acid imide are entered. The temperature is raised to 95-100" C., and the whole is stirred at that temperature for 4 hours, allowed to cool and poured on to water and ice. The dye acid is filtered off and washed with saltwater.

The moist residue is suspended in water, and adjusted with dilute sodium hydroxide solution to a pH=7.5 so that the volume amounts to about 400 parts. 200 parts by volume of 2 N-sodium hydroxide solution are added, and the whole is refluxed for 1 /2 hours and then, at the boil, in the course of /2 hour, 65 parts by volume of 10 N-hydrochl-oric acid are cautiously added. The whole is then heated with vigorous stirring form 2-2 /z hours at 100 C. The cooled solution is neutralised with sodium hydroxide solution to attain a Weakly alkaline reaction to brilliant yellow, and the dyestuif is salted out with sodium chloride. To purify the aminomethyl-copper-phthalocyanine-sulfonic acid formed it is dissolved in water, treated in an alkaline solution with steam, and the dyestuff is once more salted out.

Half of the dyestuff obtained in this manner is dissolved (in the form 0 fthe sodium salt) in 500 parts of water and cooled to 0-2" C. Furthermore, 3.7 parts of cyanuric chloride are dissolved with heat in acetone, and this solution is added at 1-4 C. to the well-stirred dyestuif solution. Neutralisation is performed by adding dropwise from a burette 20.5 parts by volume of 1 N-sodium hydroxide solution so that the pH is maintained at 6 to 7.3. After this amount of alkali has been consumed, 3.5 parts of 4-aminobenzene-l-sulfonic acid, dissolved in a little water in the form of the sodium salt, are added. Another parts by volume of .l N-sodium hydroxide solution are added dropwise, whereby the pH reaches 7. At the same time the temperature is slowly raised to 16-18 C. On completion of the condensation, 5-6 parts of sodium bicarbonate are added, the whole is stirred for a short time at 20 C. and the dyestufi is salted out with sodium chloride, and dried at 45-50 C. in vacuo. It dyes cotton by the method described in Example 26 blue tints.

EXAMPLE '25 2 parts of the monochloro-triazine obtained as described in paragraphs 1-3 of Example 3 are dissolved with 80 parts of trisodium phosphate in 400 parts of water and made up to 4000 parts. 80 parts of sodium chloride are added, and 100 parts of a cotton fabric are entered in the dyebath thus prepared. In the course of /2 hour the temperature is raised to 60 C., another 80 parts of sodium chloride are added, the temperature is raised within 15 minutes to C., and the-whole is kept at that temperature for A: hour. The blue dyeing thus obtained is then rinsed and soaped for 15 minutes in a boiling 0.3% solution of a non-ionogenic detergent; it has outstanding properties of fastness.

EXAMPLE 26 1 part of the dyestufi obtained as described in para graphs 1-3 of Example 4 is dissolved in parts of water. This solution is used to impregnate at 80 C. a cotton fabric on the padder, and the excess moisture is squeezed off so that the fabric retains 75 percent of its own weight of the dyestutf solution. The impregnated fabric is dried and at room temperature impregnated with a solution containing per liter '10 grams of sodium hydroxide and 30 0 grams of sodium chloride, squeezed to a moisture content of 75% and steamed for 60 seconds at 100-101 C., then rinsed, treated with sodium bicarbonate solution of 0.5 percent strength, soaped for 15 minutes in a 0.3% solution of a non-ionogenic detergent at the boil, rinsed and dried. A brilliant blue dyeing is obtained which is fast to washing at the boil.

EXAMPLE 27 2 parts of the primary condensation product of phthalocyanine and cyanuric chloride obtained according to Example 1 are dissolved in 2000 parts of water, 100 parts of 'well-wetted cotton yarn are entered in this dyebath at 20 to 45 C. In the course of 30 minutes 500 parts of a 20% sodium chloride solution and parts of a 10% sodium carbonate solution are added portion wise. After another 10 minutes 30 parts of a 10% sodium hydroxide solution are added, and dyeing is continued for another 60 minutes at 20 to 45 C. The dyeing so obtained is rinsed in cold water, soaped for 15 minutes at 85 to 100 C., thoroughly rinsed in cold water, and dried. A pure blue dyeing of very good fastness to light and washing is obtained.

Instead of sodium carbonate trisodium phosphate can be used with equally good results.

EXAMPLE 28 3 parts of the dyestufl obtained as described in Example 19 and 2 parts of sodium carbonate are dissolved in 25 parts of urea, and 75 parts of Water. This solution is used to impregnate a cotton fabric, which is then squeezed to a 75 percent increment in weight and dried at 80 C.

The fabric is then exposed to dry heat at C. for about 5 minutes, rinsed and soaped at the boil. A green dyeing is obtained which is fast to washing at the boil.

EXAMPLE 29 30 parts of the dyestuff obtained as described in Example 6 are dissolved in 339 parts of water, parts of urea are added, the mixture is introduced into a sodium alginate thickening, 30 parts of potassium carbonate and 1 part of a sodium hydroxide solution of 40 percent by volume strength are added. The printing paste thus obtained is used to print a cotton fabric in the usual manner and then dried, steamed for 5 minutes at 100- 101 C., rinsed, soaped, once more rinsed and dried. A brilliant blue print is thus obtained.

What is claimed is:

Compounds of the formula N CHg-NH N [Copper Phthalocyanine L 01 J 19 i 20 in which m is a number from '1'-4 and n is a number 760,347 Great Britain Oct. 31, 1956 from 2-3. 578,014 Great Britain June 12, 1946 References Cited in the file of this patent OTHER REFERENCES UNITED STATES PATENTS 5 Venkataraman: Synthetic Dyes, vol. 1, p.583, Academic 2,459,771 Pox Ian. 18, 1949 Press 1952- 2,795,584 Martin et a1. June 11, 1957 'Bergmann: The Chemistry of Acetylene and Related 2 863 875 .Bienert et a1 Dec 9 1958 Compounds, page 80, Interscience Publishers, Inc., N.Y.,

FOREIGN PATENTS 10 1,128,353 France Aug. 20, 1956 UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3,082,207 March 19, 1963 Eugen Johann Koller It is hereby certified that error appears in the above numbered patent requiring correction and that the said Letters Patent should read as corrected below.

Column 4, line 27, for "at" read to line 32, for "polyhdroxylated" read polyhydroxylated column 6. line 46, for "sold" read cold column 7, line 67, for "dystuff" read dyestuff column 9, line 27, for "hole" read whole line 43, strike out "A"; column 16, EXAMPLE 23, the left-hand portion of the formula should: appear as shown below instead of as in the patent:

column l7 line 11, for "if" read of line 39, for "form" read for Signed and sealed this 21st day of January 1964.

(SEAL) Attest: EDWIN L. REYNOLDS ERNEST W. SWIDER Attesting Officer Acting Commissioner of Patents 

